Nitrogen → 2,2-Dimethyloctanoic acid

HRID 1107714Notes

Reaction equation

HRID 1107714 reaction equation
[CH3:1][C:2]([CH3:12])([CH:6]=[CH:7][CH2:8][CH2:9][CH2:10][CH3:11])[C:3]([OH:5])=[O:4].N#N>C(O)C.[Pd]>[CH3:1][C:2]([CH3:12])([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[C:3]([OH:5])=[O:4]

Participants

5

Reactant 2

HCID 947NitrogenHCID 541965092,2-Dimethyl-3-octenoic acid

Product 1

HCID 628472,2-Dimethyloctanoic acid

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

2,2-Dimethyl octanoic acid is prepared by dissolving 2,2-dimethyl-3-octenoic acid (0.20 g, 1.1 mmol) in absolute ethanol blanketed with N2 and 10% palladium on carbon which is then hydrogenated for 6 hours. The catalyst is removed by filtration and the filtrate concentrated under vacuum to give 2,2-dimethyl octanoic acid.

Workup

  1. custom2,2-Dimethyl octanoic acid is prepared
  2. customThe catalyst is removed by filtration
  3. concentrationthe filtrate concentrated under vacuum

Sources & evidence

ORD record
ord-69857e3d0a504371a5d37ddacd51354a
Source dataset
uspto-grants-2000_05
Patent number
US06063793

Reaction notes

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