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HRID1109807

反应详情

EQUATION

反应方程式

HRID 1109807 的结构方程式

REACTANTS

反应物

3
结构：CCN(CC)CC
HCID8471

Triethylamine

C6H15N

结构：O=P([O-])([O-])O.[Na+].[Na+]
HCID24203

Dibasic sodium phosphate

HNa2O4P

结构：CS(=O)(=O)[C@@H]1C[C@@H](C(O)=S)N(C(=O)OCc2ccc([N+](=O)[O-])cc2)C1
HCID178504907

未命名化合物

PRODUCTS

生成物

1
结构：O=C1S[C@H]2C[C@@H]1N(C(=O)OCc1ccc([N+](=O)[O-])cc1)C2
HCID9904687

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：ClCCl
溶剂HCID6344

Dichloromethane

CH2Cl2

结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

For example, (2S,4R)-1-p-nitrobenzyloxycarbonyl -4-methanesulfonyl-2-pyrrolidinethiocarboxylic acid is allowed to react with disodium hydrogenphosphate or triethylamine in methylene chloride or tetrahydrofuran, thereby to give (1S,4S)-5-p-nitrobenzyloxycarbonyl-2-thia-5-azabicyclo[2.2.1]heptan-3-one.