Azobisisobutyronitrile → Methyl Methacrylate

HRID 1111430Notes

Reaction equation

HRID 1111430 reaction equation
[C:1]([O:6][CH2:7][CH2:8][O:9]C(=O)C(C)=C)(=[O:5])[C:2]([CH3:4])=[CH2:3].N(C(C)(C)C#N)=NC(C)(C)C#N>>[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:1]([O:6][CH2:7][CH2:8][OH:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:1]([O:6][CH2:7][CH3:8])(=[O:5])[C:2]([CH3:4])=[CH2:3]

Participants

5

Reactant 2

HCID 6547AzobisisobutyronitrileHCID 7355Ethylene glycol dimethacrylate

Product 3

HCID 6658Methyl MethacrylateHCID 7343Ethyl MethacrylateHCID 133602-Hydroxyethyl Methacrylate

Procedure

Into a test tube, were placed 50 g of polymerizable monomer containing silicon containing compound (A) obtained in Manufacturing Example 1, 25g of methyl methacrylate, 10 g of ethyleneglycol monomethacrylate, 5g of ethyleneglycol dimethacrylate, 10 g of ethyl methacrylate and 0.lg of azobisisobutyronitrile and after purging the air with nitrogen gas, the tube was sealed. The content was polymerized by UV irradiation at 40° C. for 18 hours and then by heating at 110° C. for 6 hours to obtain a colorless, solid stick, vinyl polymer containing silicon.

Workup

  1. customInto a test tube, were placed
  2. addition50 g of polymerizable monomer containing silicon containing compound (A)

Sources & evidence

ORD record
ord-f5edbe4f453c42d381dee86da5007446
Source dataset
uspto-grants-1990_12
Patent number
US04980442

Reaction notes

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