Acetone → Diethyl isopropylidenemalonate

HRID 1136895Notes

Reaction equation

HRID 1136895 reaction equation
[C:1]([CH2:2][C:3](=[O:4])[O:5][CH2:6][CH3:7])(=[O:8])[O:9][CH2:10][CH3:11].[CH3:12][C:13]([CH3:14])=[O:15].[CH3:16][C:17]([O:18][C:19](=[O:20])[CH3:21])=[O:22].[Cl-:23].[Cl-:25].[Zn+2:24].[cH:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1>>[C:1]([C:2]([C:3](=[O:4])[O:5][CH2:6][CH3:7])=[C:13]([CH3:12])[CH3:14])(=[O:8])[O:9][CH2:10][CH3:11]

Participants

7

Reactant 6

HCID 180AcetoneHCID 241BenzeneHCID 312Chloride2×HCID 7761Diethyl MalonateHCID 7918Acetic AnhydrideHCID 32051Zinc(2+)

Product 1

HCID 81255Diethyl isopropylidenemalonate

Sources & evidence

ORD record
ord-bae6c59ea982478c9489b375da680026
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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