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HRID1156449

反应详情

EQUATION

反应方程式

HRID 1156449 的结构方程式

REACTANTS

反应物

7
结构：CN1C(C)(C)CCCC1(C)C
HCID6603

Pempidine

C10H21N

结构：CCCCCCCCN(CCCCCCCC)CCCCCCCC
HCID14227

Trioctylamine

C24H51N

结构：CCN(C1CCCCC1)C1CCCCC1
HCID23563

Cyclohexanamine, N-cyclohexyl-N-ethyl-

C14H27N

结构：CCN(C(C)C)C(C)C
HCID81531

Diisopropylethylamine

C8H19N

结构：CCCCC(CC)CN(CC(CC)CCCC)CC(CC)CCCC
HCID102705

1-Hexanamine, 2-ethyl-N,N-bis(2-ethylhexyl)-

C24H51N

结构：CC(=O)[O-].[Li+]
HCID3474584

Acetic acid, lithium salt (1:1)

C2H3LiO2

结构：CC(=O)[O-].C[N+](C)(C)Cc1ccccc1
HCID13086341

N,N,N-Trimethyl(phenyl)methanaminium acetate

C12H19NO2

PRODUCTS

生成物

1
结构：CCOC(=O)C=Cc1ccccc1
HCID7649

Ethyl cinnamate

C11H12O2

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCN(CC)CC
溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

The procedure described in Example 1 is repeated, except that 0.03125 mol of one of the bases tri-n-octylamine, tris-(2-ethylhexyl)-amine, ethyl-dicyclohexylamine, triethylamine, ethyl-diisopropylamine, N-methyl-2,2,6,6-tetramethylpiperidine, lithium acetate and trimethyl-benzylammonium acetate is used in place of 0.03125 mol of tri-n-butylamine. After working up as described in Example 1, ethyl cinnamate is obtained in comparably good yields.