Methyl Acrylate → HCID 54367761, compound

HRID 1156455Notes

Reaction equation

HRID 1156455 reaction equation
[CH2:1](Cl)[CH:2]=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[C:11]([O:15][CH3:16])(=[O:14])[CH:12]=[CH2:13]>>[C:4]1([CH:3]=[CH:2][CH:1]=[CH:13][CH2:12][C:11]([O:15][CH3:16])=[O:14])[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Participants

3

Reactant 2

HCID 7294Methyl AcrylateHCID 94242Benzene, (3-chloro-1-propenyl)-

Product 1

HCID 54367761HCID 54367761, compoundYield 65%

Procedure

The procedure described in Example 28 is repeated, except that 8.35 g (0.05 mol) of cinnamyl chloride and 5.4 g (0.0625 mol) of methyl acrylate are used. After a reaction time of 50 hours at 120° C., 6.10 g (0.0325 mol) of methyl 5-phenyl-2.4-pentadienecarboxylate are obtained, corresponding to a yield of 65% of theory; melting point 71° C.

Sources & evidence

ORD record
ord-6bdeb6f6e8024d37aeb2e8394f49b67d
Source dataset
uspto-grants-1982_06
Patent number
US04335054

Reaction notes

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