Sodium Sulfite → HCID 86622428, compound

HRID 1186448Notes

Reaction equation

HRID 1186448 reaction equation
[S:1]([O-:4])([O-:3])=[O:2].[Na+:5].[Na+].Br[CH2:8][CH:9]1[CH2:11][CH2:10]1>O>[CH:9]1([CH2:8][S:1]([O-:4])(=[O:3])=[O:2])[CH2:11][CH2:10]1.[Na+:5]

Participants

4

Reactant 2

HCID 24437Sodium SulfiteHCID 81503Bromomethylcyclopropane

Product 1

HCID 86622428HCID 86622428, compoundYield 128.9%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
100 °C

Procedure

Sodium sulfite (1.43 g, 11.3 mmol) was dissolved in water (8.00 mL). To this, (bromomethyl)cyclopropane (1.00 mL, 10.3 mmol) was added and the mixture was stirred with heat at 100° C. for 24 hours. The solvent in the reaction mixture was evaporated off under reduced pressure, and the residue was subjected to slurry purification using diisopropyl ether, to give sodium cyclopropanemethanesulfonate (2.10 g, yield: 99%).

Workup

  1. customThe solvent in the reaction mixture was evaporated off under reduced pressure
  2. custompurification

Sources & evidence

ORD record
ord-6d93072c963547d6a12f618a3967d262
Source dataset
uspto-grants-2014_03
Patent number
US08673908B2

Reaction notes

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