Carbon Dioxide → HCID 19105159, compound

HRID 1197816Notes

Reaction equation

HRID 1197816 reaction equation
[F:1][C:2]([F:17])([F:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13](O)=[O:14].C(Cl)(=O)C([Cl:21])=O.C(=O)=O>C(Cl)Cl.CN(C)C=O>[F:1][C:2]([F:17])([F:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([Cl:21])=[O:14]

Participants

6

Reactant 3

HCID 280Carbon DioxideHCID 65578Oxalyl chlorideHCID 981373812,12,12-trifluorododecanoic Acid

Product 1

HCID 19105159HCID 19105159, compound

Reagents, catalysts & solvents 2

HCID 6228DimethylformamideCatalystHCID 6344DichloromethaneSolvent

Procedure

Dissolve 12,12,12-trifluorododecanoic acid (244 mg, 0.96 mmol) in methylene chloride (5 mL) and add dimethylformamide (3 drops). Add oxalyl chloride (85 μL, 0.96 mmol) and stir until evolution of carbon dioxide is complete to give 12,12,12-trifluorododecanoyl chloride.

Sources & evidence

ORD record
ord-248f6bbd21be480d8a0440942da7b465
Source dataset
uspto-grants-1994_01
Patent number
US05278171

Reaction notes

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