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HRID1199468

反应详情

EQUATION

反应方程式

HRID 1199468 的结构方程式

REACTANTS

反应物

2
结构：O=C(OO)c1cccc(Cl)c1
HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：COc1cc2ccnc(-c3ccccc3Sc3nc4ccccc4[nH]3)c2cc1OC
HCID19866631

未命名化合物

PRODUCTS

生成物

1
结构：COc1cc2ccnc(-c3ccccc3S(=O)c3nc4ccccc4[nH]3)c2cc1OC
HCID15059540

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：O=C([O-])O.[Na+]
溶剂HCID516892

Sodium Bicarbonate

CHNaO3

结构：ClC(Cl)Cl.ClCCl
溶剂HCID18399249

未命名化合物

PROCEDURE

实验过程

The product of step (f) above was dissolved in 1:1 CH2Cl2 -CHCl3 (10 ml), treated with 85%m-Chloroperbenzoic acid (24 mg) at -5°, and worked up in aqueous NaHCO3 to give the title compound. NMR (CDCl3)d, 8.5 (d,1H), 8.35 (dd,1H), 7.26 (1H,s), 7.21 (1H,s), 7.7-7.2 (complex,8H), 4.30 (s,3H), 3.85 (s,3H)ppm, mp 250° (d).