m-Chloroperbenzoic acid → HCID 19866663, compound

HRID 1199470Notes

Reaction equation

HRID 1199470 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][N:6]=[C:5]([C:9]2[S:10][CH:11]=[CH:12][C:13]=2[S:14][CH3:15])[CH:4]=1.ClC1C=CC=C(C(OO)=[O:24])C=1>C(OCC)(=O)C>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][N:6]=[C:5]([C:9]2[S:10][CH:11]=[CH:12][C:13]=2[S:14]([CH3:15])=[O:24])[CH:4]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 19866712HCID 19866712, compound

Product 1

HCID 19866663HCID 19866663, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

The product of step (c) above was dissolved in ethyl acetate (100 ml) and cooled to -10°. m-Chloroperbenzoic acid (2.98 g) was added and after 1.5 hour the mixture was worked-up then chromatographed (ethyl acetate) to give the sub-title compound as a solid, mp 103°-105°.

Workup

  1. temperaturecooled to -10°
  2. customwas worked-up then chromatographed (ethyl acetate)

Sources & evidence

ORD record
ord-7a3e757582a046f29bbc066809eabf2a
Source dataset
uspto-grants-1990_02
Patent number
US04900751

Reaction notes

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