Acetate → Ethyl 3-[4-[(4-hydroxyphenyl)-(2,2,6,6-tetramethyloxan-4-ylidene)methyl]phenyl]prop-2-enoate

HRID 1215233Notes

Reaction equation

HRID 1215233 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8]([c:9]2[cH:10][cH:11][c:12]([OH:15])[cH:13][cH:14]2)=[C:16]2[CH2:17][C:18]([CH3:24])([CH3:25])[O:19][C:20]([CH3:22])([CH3:23])[CH2:21]2)[cH:6][cH:7]1.[C:26]([CH:27]=[CH2:28])(=[O:29])[O:30][CH2:31][CH3:32].[CH3:33][CH2:34][N:35]([CH2:36][CH3:37])[CH2:38][CH3:39].[O-:41][C:42]([CH3:43])=[O:44].[O-:45][C:46]([CH3:47])=[O:48].[O:49]=[CH:50][N:51]([CH3:52])[CH3:53].[Pd+2:40]>>[c:2]1([CH:28]=[CH:27][C:26](=[O:29])[O:30][CH2:31][CH3:32])[cH:3][cH:4][c:5]([C:8]([c:9]2[cH:10][cH:11][c:12]([OH:15])[cH:13][cH:14]2)=[C:16]2[CH2:17][C:18]([CH3:24])([CH3:25])[O:19][C:20]([CH3:22])([CH3:23])[CH2:21]2)[cH:6][cH:7]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6228DimethylformamideHCID 8471TriethylamineHCID 8821Ethyl AcrylateHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 686543254-[(4-Bromophenyl)(2,2,6,6-tetramethyltetrahydro-4H-pyran-4-ylidene)methyl]phenol

Product 1

HCID 77583442Ethyl 3-[4-[(4-hydroxyphenyl)-(2,2,6,6-tetramethyloxan-4-ylidene)methyl]phenyl]prop-2-enoate

Sources & evidence

ORD record
ord-abc672aa68c84590a122d16d8896cde7
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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