Sulfuric Acid → 5-Bromo-3-pyridinecarboxaldehyde

HRID 1215592Notes

Reaction equation

HRID 1215592 reaction equation
[Al+3:2].[Br:22][c:23]1[cH:24][c:25]([C:29](=[O:30])[OH:31])[cH:26][n:27][cH:28]1.[CH2:37]1[O:38][CH2:39][CH2:40][CH2:41]1.[CH3:7][CH2:8][O:9][C:10](=[O:11])[CH3:12].[H-:1].[H-:4].[H-:5].[H-:6].[Li+:3].[O:13]1[CH2:14][CH2:15][NH:16][CH2:17][CH:18]1[C:19]([NH2:20])=[O:21].[S:32](=[O:33])(=[O:34])([OH:35])[OH:36]>>[Br:22][c:23]1[cH:24][c:25]([CH:29]=[O:30])[cH:26][n:27][cH:28]1

Participants

9

Reactant 8

HCID 1118Sulfuric AcidHCID 8028TetrahydrofuranHCID 8857Ethyl AcetateHCID 28486Lithium ionHCID 887075-Bromonicotinic acidHCID 104727Aluminum CationHCID 166653Hydride4×HCID 15955786Morpholine-2-carboxamide

Product 1

HCID 27847345-Bromo-3-pyridinecarboxaldehyde

Sources & evidence

ORD record
ord-3c89f3ed3316496b9bb818e702e2440e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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