Acetate → Methyl 6-cyanonaphthalene-2-carboxylate

HRID 1219806Notes

Reaction equation

HRID 1219806 reaction equation
[C:1](#[N:2])[c:3]1[cH:4][c:5]2[cH:6][cH:7][c:8]([O:13][S:14]([C:15]([F:16])([F:17])[F:18])(=[O:19])=[O:20])[cH:9][c:10]2[cH:11][cH:12]1.[CH3:40][CH2:41][N:42]([CH2:43][CH3:44])[CH2:45][CH3:46].[CH3:47][OH:48].[O-:55][C:56]([CH3:57])=[O:58].[O-:59][C:60]([CH3:61])=[O:62].[O:49]=[CH:50][N:51]([CH3:52])[CH3:53].[Pd+2:54].[c:21]1([P:22]([c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)[c:29]2[cH:30][cH:31][cH:32][cH:33][cH:34]2)[cH:35][cH:36][cH:37][cH:38][cH:39]1>>[C:1](#[N:2])[c:3]1[cH:4][c:5]2[cH:6][cH:7][c:8]([C:50]([O:48][CH3:47])=[O:49])[cH:9][c:10]2[cH:11][cH:12]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 887MethanolHCID 6228DimethylformamideHCID 8471TriethylamineHCID 11776TriphenylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 155418226-Cyano-2-naphthyl trifluoromethanesulfonate

Product 1

HCID 12433083Methyl 6-cyanonaphthalene-2-carboxylate

Sources & evidence

ORD record
ord-ccddf9b882e34777abd913e9e0260400
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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