Triphenylphosphine → HCID 67314508, compound

HRID 1223536Notes

Reaction equation

HRID 1223536 reaction equation
[C:45](#[CH:46])[Si:47]([CH3:48])([CH3:49])[CH3:50].[Cu:107][I:108].[NH2:1][c:2]1[c:3]([NH:8][c:9]2[cH:10][c:11]([Cl:25])[c:12]([C:15](=[O:16])[c:17]3[c:18]([CH3:24])[cH:19][cH:20][c:21]([Br:23])[cH:22]3)[cH:13][cH:14]2)[cH:4][cH:5][cH:6][cH:7]1.[O:53]=[C:54]([CH:55]=[CH:56][c:57]1[cH:58][cH:59][cH:60][cH:61][cH:62]1)[CH:63]=[CH:64][c:65]1[cH:66][cH:67][cH:68][cH:69][cH:70]1.[O:71]=[C:72]([CH:73]=[CH:74][c:75]1[cH:76][cH:77][cH:78][cH:79][cH:80]1)[CH:81]=[CH:82][c:83]1[cH:84][cH:85][cH:86][cH:87][cH:88]1.[O:89]=[C:90]([CH:91]=[CH:92][c:93]1[cH:94][cH:95][cH:96][cH:97][cH:98]1)[CH:99]=[CH:100][c:101]1[cH:102][cH:103][cH:104][cH:105][cH:106]1.[Pd:51].[Pd:52].[c:26]1([P:27]([c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[cH:40][cH:41][cH:42][cH:43][cH:44]1>>[NH2:1][c:2]1[c:3]([NH:8][c:9]2[cH:10][c:11]([Cl:25])[c:12]([C:15](=[O:16])[c:17]3[c:18]([CH3:24])[cH:19][cH:20][c:21]([C:46]#[C:45][Si:47]([CH3:48])([CH3:49])[CH3:50])[cH:22]3)[cH:13][cH:14]2)[cH:4][cH:5][cH:6][cH:7]1

Participants

7

Reactant 6

HCID 11776TriphenylphosphineHCID 23938Palladium2×HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 95417Dibenzylidene acetone3×HCID 67314056HCID 67314056, compound

Product 1

HCID 67314508HCID 67314508, compound

Sources & evidence

ORD record
ord-a2c48581b9e04b56b9f590e11b0f7053
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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