Methyl Methacrylate → HCID 178454695, Verbindung

HRID 1249485Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1249485
[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH:8]1[CH:9]=[CH:10][N+:11]([O-:15])=[C:12]([SH:14])[CH:13]=1.C([O-])(=O)C(C)=C>C1(C)C=CC=CC=1.C(Cl)Cl.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.O>[CH:8]1[CH:9]=[CH:10][N+:11]([O-:15])=[C:12]([SH:14])[CH:13]=1.[C:1]([O-:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3]

Komponenten

7

Edukt 2

HCID 6658Methyl MethacrylateHCID 178454790HCID 178454790, Verbindung

Produkt 1

HCID 178454695HCID 178454695, VerbindungAusbeute 155,3 %

Reagenzien, Katalysatoren, Lösungsmittel 4

HCID 962WaterKatalysatorHCID 7187Benzoyl PeroxideKatalysatorHCID 1140TolueneLösungsmittelHCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

A 150-ml flask was charged with 60.6 g of methyl methacrylate (0.6 mole), 26.4 g of pyrithione methacrylate (0.135 mole), 3.69 g of 70% benzoyl peroxide in water (0.011 mole) and 60 ml of toluene. The flask was sealed and placed in an oven at 85° C. for 16 hours. After cooling to room temperature the product was diluted with 60 ml of methylene chloride and filtered. The solution was concentrated via roto-evaporation and 65.49 g of the desired product was isolated as a yellow polymeric solid for a 73.1% yield.

Aufarbeitung

  1. customThe flask was sealed
  2. filtrationfiltered
  3. concentrationThe solution was concentrated via roto-evaporation

Quellen und Nachweise

ORD-Eintrag
ord-c3bbef7d81c44b2c830e40911d3f3e76
Quelldatensatz
uspto-grants-1986_12
Patentnummer
US04632881

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