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HRID1283116

反应详情

EQUATION

反应方程式

HRID 1283116 的结构方程式

REACTANTS

反应物

4
结构：CN(C)C=O
HCID6228

N,N-Dimethylformamide

C3H7NO

结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

结构：CCOC(=O)CC(C(=O)OCC)C(=O)OCC
HCID81961

Triethyl ethane-1,1,2-tricarboxylate

C11H18O6

结构：Cc1cccc([N+](=O)[O-])c1CCl
HCID12204070

Benzene, 2-(chloromethyl)-1-methyl-3-nitro-

C8H8ClNO2

PRODUCTS

生成物

1
结构：CCOC(=O)CC(Cc1c(C)cccc1[N+](=O)[O-])(C(=O)OCC)C(=O)OCC
HCID21519363

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

The title compound was prepared by the same procedure as described in example 1 for 1a (R2 = R3 = H), using triethyl 1,1,2-ethanetricarboxylate (9.85 g; 0.04 mole), NaH (1.6 g; 0.04 mole) and 2-nitro-6-methylbenzyl chloride (7.4 g; 0.04 mole) in 20 ml. 10% dimethylformamide (DMF) in benzene. The crude product so obtained was used directly in the next step without further purification.