1-Bromooctane → HCID 54426749, compound

HRID 1283367Notes

Reaction equation

HRID 1283367 reaction equation
[CH3:1][C:2]1([CH3:10])[CH2:7][CH2:6][CH2:5][C:4]([CH3:9])([CH3:8])[NH:3]1.Br[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]>>[CH2:12]([N:3]1[C:4]([CH3:9])([CH3:8])[CH2:5][CH2:6][CH2:7][C:2]1([CH3:10])[CH3:1])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

Participants

3

Reactant 2

HCID 81401-BromooctaneHCID 130352,2,6,6-Tetramethylpiperidine

Product 1

HCID 54426749HCID 54426749, compound

Procedure

A mixture of 56.4 parts of 2,2,6,6-tetramethylpiperidine and 38.6 parts of 1-bromooctane was heated at 125°-30°C for 120 hours. The cooled reaction mixture was filtered to remove 2,2,6,6-tetramethylpiperidine hydrobromide formed during the reaction. Fractional distillation of the residue gave 1-n-octyl-2,2,6,6-tetramethylpiperidine having a boiling point of 168°C/17 mm of Hg.

Workup

  1. temperaturewas heated at 125°-30°C for 120 hours
  2. customThe cooled reaction mixture
  3. filtrationwas filtered
  4. customto remove 2,2,6,6-tetramethylpiperidine hydrobromide
  5. customformed during the reaction
  6. distillationFractional distillation of the residue

Sources & evidence

ORD record
ord-f26e526e9ffa424db66d0a3053336c8e
Source dataset
uspto-grants-1976_08
Patent number
US03975357

Reaction notes

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