Chlorotrimethylsilane → HCID 12472499, compound

HRID 1284320Notes

Reaction equation

HRID 1284320 reaction equation
[NH:1]1[CH2:5][CH2:4][NH:3][C:2]1=[S:6].[CH3:7][Si:8]([CH3:11])([CH3:10])Cl.C(N(CC)CC)C>O1CCCC1>[CH3:7][Si:8]([CH3:11])([CH3:10])[N:1]1[CH2:5][CH2:4][NH:3][C:2]1=[S:6]

Participants

5

Reactant 3

HCID 6397ChlorotrimethylsilaneHCID 8471TriethylamineHCID 2723650Ethylenethiourea

Product 1

HCID 12472499HCID 12472499, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

30.6 parts by weight of imidazolidine-2-thione were boiled overnight with 54.4 parts by weight of trimethylchlorosilane and 51.5 parts by weight of triethylamine in absolute tetrahydrofurane. The warm suspension was freed of the precipitated triethylamine hydrochloride by filtration, and the filtrate was evaporated and dried in a vacuum desiccator.

Workup

  1. filtrationThe warm suspension was freed of the precipitated triethylamine hydrochloride by filtration
  2. customthe filtrate was evaporated
  3. customdried in a vacuum desiccator

Sources & evidence

ORD record
ord-f69b391e25f540d7a1685f1175b1bffa
Source dataset
uspto-grants-1976_08
Patent number
US03978223

Reaction notes

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