4-Chlororesorcinol → HCID 58913587, compound

HRID 1296888Notes

Reaction equation

HRID 1296888 reaction equation
[Cl:1][C:2]1[CH:8]=[CH:7][C:5]([OH:6])=[CH:4][C:3]=1[OH:9].[CH3:10][O:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=1[CH2:18][C:19]([OH:21])=O.P(Cl)(Cl)(Cl)(Cl)Cl.[CH3:28]N(C=O)C>>[Cl:1][C:2]1[CH:8]=[C:7]2[C:5](=[CH:4][C:3]=1[OH:9])[O:6][CH:28]=[C:18]([C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][C:12]=1[O:11][CH3:10])[C:19]2=[O:21]

Participants

5

Reactant 4

HCID 17314-ChlororesorcinolHCID 6228DimethylformamideHCID 71342-Methoxyphenylacetic acidHCID 24819Phosphorus pentachloride

Product 1

HCID 58913587HCID 58913587, compound

Procedure

This compounds was synthesised in the same manner as described above. 4-Chlororesorcinol (1.74 g, 12.0 mmol), 2-methoxyphenylacetic acid (2.0 g, 12.0 mmol), BF3Et2O (10 ml), PCl5 (3.76 g, 18.1 mmol), DMF (20 ml and 10 ml). The pale brown solid precipitate was taken directly onto the next stage without further purification.

Workup

  1. customThis compounds was synthesised in the same manner
  2. customThe pale brown solid precipitate was taken directly onto the next stage without further purification

Sources & evidence

ORD record
ord-c87310f3a2124578ae00ff562c387848
Source dataset
uspto-grants-2007_07
Patent number
US07247734B2

Reaction notes

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