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HRID1355828

反应详情

EQUATION

反应方程式

HRID 1355828 的结构方程式

REACTANTS

反应物

5
结构：CC(=O)c1ccco1
HCID14505

2-Acetylfuran

C6H6O2

结构：O=C1CCC(=O)N1Br
HCID67184

1-Bromopyrrolidine-2,5-dione

C4H4BrNO2

结构：COC(OC)N(C)C
HCID78373

Methanamine, 1,1-dimethoxy-N,N-dimethyl-

C5H13NO2

结构：N=C(N)N.O=C(O)O
HCID286947

Carbonic acid--guanidine (1/1)

C2H7N3O3

结构：C[O-].[Na+]
HCID10942334

Methanol, sodium salt

CH3NaO

PRODUCTS

生成物

1
结构：Nc1ncc(Br)c(-c2ccco2)n1
HCID18507263

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

3
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

结构：CO
溶剂HCID887

Methanol

CH4O

结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

From 2-acetylfuran and N,N-dimethylformamide dimethyl acetal in DMF. Then treatment with guanidine carbonate and sodium methylate in methanol. Then treatment with N-bromosuccinimide in acetic acid. EI-MS m/e (%): 241 (M{81Br}+, 98), 239 (M{81Br}+, 100).