HRID13867

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID13529

2H-Perfluoro-2-propanol

C3H2F6O

HCID83681

Tris(1,1-dimethylethyl)phosphine

C12H27P

结构：[Na+].c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID2723787

Borate(1-), tetraphenyl-, sodium

C24H20BNa

PRODUCTS

生成物

结构：CC(C)(C)[PH+](C(C)(C)C)C(C)(C)C.c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID23136663

Tri-tert-butylphosphanium tetraphenylborate(1-)

C36H48BP

收率 77%

PROCEDURE

实验过程

Tri-tert-butylphosphine is reacted with 1,1,1,3,3,3-hexafluoro-2-propanol and with sodium tetraphenylborate to produce tri-tert-butylphosphonium tetraphenylborate (77% yield). A similar process is described in which tricyclohexylphosphine is used as starting material to produce tricyclohexylphosphonium tetraphenylborate (77% yield) (see Nonpatent Document 7).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-32062efb59614351b3cd53ae313ef854
来源数据集: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07728176B2
来源说明: uspto-grants-2010_06

反应 SMILES

[C:1]([P:5]([C:10]([CH3:13])([CH3:12])[CH3:11])[C:6]([CH3:9])([CH3:8])[CH3:7])([CH3:4])([CH3:3])[CH3:2].FC(F)(F)C(O)C(F)(F)F.[C:24]1([B-:30]([C:43]2[CH:48]=[CH:47][CH:46]=[CH:45][CH:44]=2)([C:37]2[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=2)[C:31]2[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=2)[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1.[Na+]>>[C:43]1([B-:30]([C:24]2[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=2)([C:31]2[CH:32]=[CH:33][CH:34]=[CH:35][CH:36]=2)[C:37]2[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=2)[CH:44]=[CH:45][CH:46]=[CH:47][CH:48]=1.[C:10]([PH+:5]([C:1]([CH3:4])([CH3:3])[CH3:2])[C:6]([CH3:9])([CH3:8])[CH3:7])([CH3:11])([CH3:12])[CH3:13]