HRID13868

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID313

Hydrochloric Acid

ClH

HCID13831

Tributylphosphine

C12H27P

结构：[Na+].c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID2723787

Borate(1-), tetraphenyl-, sodium

C24H20BNa

PRODUCTS

生成物

结构：CCCC[PH+](CCCC)CCCC.c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID23136640

未命名化合物

收率 53%

PROCEDURE

实验过程

Tri-n-butylphosphine is reacted with hydrochloric acid in the presence of sodium tetraphenylborate to produce tri-n-butylphosphonium tetraphenylborate (53% yield) (see Nonpatent Document 6).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-0b6a244a31ae4bdea68240493807b244
来源数据集: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07728176B2
来源说明: uspto-grants-2010_06

反应 SMILES

[CH2:1]([P:5]([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].Cl.[C:15]1([B-:21]([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[Na+]>>[C:34]1([B-:21]([C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=2)([C:22]2[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=2)[C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[CH:35]=[CH:36][CH:37]=[CH:38][CH:39]=1.[CH2:10]([PH+:5]([CH2:1][CH2:2][CH2:3][CH3:4])[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:11][CH2:12][CH3:13]