Tert-Butyl nitrite → HCID 351512, compound

HRID 1419714Notes

Reaction equation

HRID 1419714 reaction equation
CS[S:3][CH3:4].N(OC(C)(C)C)=O.N[C:13]1[S:14][C:15]2[CH:21]=[C:20]([Cl:22])[CH:19]=[C:18]([Cl:23])[C:16]=2[N:17]=1>ClCCCl>[Cl:23][C:18]1[C:16]2[N:17]=[C:13]([S:3][CH3:4])[S:14][C:15]=2[CH:21]=[C:20]([Cl:22])[CH:19]=1

Participants

5

Reactant 3

HCID 10906Tert-Butyl nitriteHCID 12232Dimethyl DisulfideHCID 1127224,6-Dichloro-1,3-benzothiazol-2(3H)-imine

Product 1

HCID 351512HCID 351512, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

43.7 g (0.47 mol) of dimethyl disulfide and 154.5 g (1.5 mol) of tert-butyl nitrite were added to a solution of 34 g (0.16 mol) of 2-amino-4,6-dichlorobenzothiazole in 1 liter of 1,2-dichloroethane. Stirring was carried out for 16 hours, followed by washing with water and 10% strength sodium hydroxide solution, drying over magnesium sulfate and evaporating down.

Workup

  1. washby washing with water and 10% strength sodium hydroxide solution
  2. dry with materialdrying over magnesium sulfate
  3. customevaporating down

Sources & evidence

ORD record
ord-211d939a71ba483abfcada8ce673dd5f
Source dataset
uspto-grants-1999_03
Patent number
US05888940

Reaction notes

Loading…