Triethylamine → HCID 54328425, compound

HRID 1448082Notes

Reaction equation

HRID 1448082 reaction equation
[CH3:1][N:2]1[C:6](=[O:7])[C:5]([CH3:9])([CH3:8])[S:4][C:3]1=[N:10][OH:11].[CH3:12][N:13]([S:17][C:18]([C:21](=[O:28])[C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)([CH3:20])[CH3:19])[C:14](Cl)=[O:15].C(N(CC)CC)C>O1CCOCC1.O.C(OC(=O)C)C>[CH3:12][N:13]([S:17][C:18]([C:21](=[O:28])[C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)([CH3:20])[CH3:19])[C:14]([O:11][N:10]=[C:3]1[N:2]([CH3:1])[C:6](=[O:7])[C:5]([CH3:9])([CH3:8])[S:4]1)=[O:15]

Participants

7

Reactant 3

HCID 8471TriethylamineHCID 54012549HCID 54012549, compoundHCID 713633892-(Hydroxyimino)-3,5,5-trimethyl-1,3-thiazolidin-4-one

Product 1

HCID 54328425HCID 54328425, compound

Reagents, catalysts & solvents 3

HCID 962WaterSolventHCID 8857Ethyl AcetateSolventHCID 312751,4-DioxaneSolvent

Procedure

To a solution of 2.5 g (0.015 m) of 3,5,5-trimethyl-2-oximino-thiazolidin-4-one and 3.93 g (0.015 m) of N-methyl-N-(2-benzoyl-2-propanesulfenyl)carbamoyl chloride in 100 ml of dioxane was added 1.5 g (0.015 m) of triethylamine. After stirring at room temperature for 16 hours, the reaction mixture was diluted with water and the product isolated in ethylacetate. Recrystallized from isopropyl ether. Weight of the procut 1.3 g, m.p. 98°-100° C.

Workup

  1. customRecrystallized from isopropyl ether

Sources & evidence

ORD record
ord-cf788a3ca3664c29ac438fc48700d5af
Source dataset
uspto-grants-1979_12
Patent number
US04179514

Reaction notes

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