HCID 11143241, compound → HCID 10926072, compound

HRID 1449757Notes

Reaction equation

HRID 1449757 reaction equation
[C:1]([O:4][C@@H:5]1[C@@H:10]([O:11][C:12](=[O:14])[CH3:13])[C@H:9]([O:15][C:16](=[O:18])[CH3:17])[C@@H:8]([CH2:19][O:20][C:21](=[O:23])[CH3:22])[O:7][CH:6]1[N:24]=[N+]=[N-])(=[O:3])[CH3:2].[H][H]>O=[Pt]=O.O1CCCC1>[C:1]([O:4][C@@H:5]1[C@@H:10]([O:11][C:12](=[O:14])[CH3:13])[C@H:9]([O:15][C:16](=[O:18])[CH3:17])[C@@H:8]([CH2:19][O:20][C:21](=[O:23])[CH3:22])[O:7][CH:6]1[NH2:24])(=[O:3])[CH3:2]

Participants

5

Reactant 2

HCID 11143241HCID 11143241, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 10926072HCID 10926072, compound

Reagents, catalysts & solvents 2

HCID 345198Adams' catalystCatalystHCID 8028TetrahydrofuranSolvent

Procedure

4 g, that is, 11 mmol of the 2,3,4,6-tetra-O-acetylglucopyranosyl azide was added to 50 ml of dry tetrahydrofuran containing 200 mg of PtO2. The mixture was shaken under 40 psi of hydrogen for 2 hours, filtered, concentrated to dryness, to produce 2,3,4,6-tetra-O-acetylglucopyranosyl amine.

Workup

  1. filtrationfiltered
  2. concentrationconcentrated to dryness

Sources & evidence

ORD record
ord-77e6c079c71d49238822078c2a28b565
Source dataset
uspto-grants-1997_02
Patent number
US05599953

Reaction notes

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