Tetrahydrofuran → HCID 86749480, compound

HRID 1449758Notes

Reaction equation

HRID 1449758 reaction equation
C[C:2]1([N:23]=[N+]=[N-])[O:19][C@H:18]([C:20]([OH:22])=[O:21])[C@@H:13]([O:14][C:15](=[O:17])[CH3:16])[C@H:8]([O:9][C:10](=[O:12])[CH3:11])[C@H:3]1[O:4][C:5](=[O:7])[CH3:6].[H][H].O1CCC[CH2:29]1>O=[Pt]=O>[CH3:29][NH:23][CH:2]1[O:19][C@H:18]([C:20]([OH:22])=[O:21])[C@@H:13]([O:14][C:15](=[O:17])[CH3:16])[C@H:8]([O:9][C:10](=[O:12])[CH3:11])[C@H:3]1[O:4][C:5](=[O:7])[CH3:6]

Participants

5

Reactant 3

HCID 8028TetrahydrofuranHCID 86749481HCID 86749481, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 86749480HCID 86749480, compound

Reagents, catalysts & solvents 1

HCID 345198Adams' catalystCatalyst

Procedure

Next, 6.17 g, that is, 17 mmol methyl 2,3,4-tri-O-acetylglucopyranuronosyl azide was added to 50 ml of dry tetrahydrofuran containing 400 mg of PtO2. The mixture was shaken under 40 psi of hydrogen for 2 hours, filtered, concentrated to dryness, to produce methyl 2,3,4-tri-O-acetylglucopyranuronosyl amine. ##STR8##

Workup

  1. filtrationfiltered
  2. concentrationconcentrated to dryness

Sources & evidence

ORD record
ord-1c54eb6b07dc4f6f87685561c77a80cf
Source dataset
uspto-grants-1997_02
Patent number
US05599953

Reaction notes

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