Hydrochloric Acid → HCID 178515941, compound

HRID 1450515Notes

Reaction equation

HRID 1450515 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[OH:9])#[N:2].[Cl-].[NH4+].[N-:12]=[N+:13]=[N-:14].[Na+].Cl>CN(C)C=O>[NH:12]1[C:1]([C:3]2[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=2[OH:9])=[N:2][N:14]=[N:13]1

Participants

6

Reactant 4

HCID 313Hydrochloric AcidHCID 119072-HydroxybenzonitrileHCID 25517Ammonium ChlorideHCID 33557Sodium Azide

Product 1

HCID 178515941HCID 178515941, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Conditions

Temperature
120 °C

Procedure

2-Cyanophenol (1.19 g), ammonium chloride (0.695 g), and sodium azide (0.845 g) were added to dimethylformamide (5 ml). The mixture was heated with stirring at 120° C. for 3 h. After cooling, it was poured into ice water and acidified with dilute hydrochloric acid. The resulting crystals were collected by filtration and dried to give the title compound.

Workup

  1. temperatureThe mixture was heated
  2. temperatureAfter cooling
  3. filtrationThe resulting crystals were collected by filtration
  4. customdried

Sources & evidence

ORD record
ord-ce0b42d4813a4ca0a05b2f1886c8c46a
Source dataset
uspto-grants-1997_02
Patent number
US05602161

Reaction notes

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