Bicarbonate Ion → 5-(1,3-Benzodioxol-5-ylmethyl)-1-(4-bromophenyl)-4-hydroxy-2,3,3-trimethyl-1,3a,4,6a-tetrahydropyrrolo[3,4-c]pyrrol-6-one

HRID 149240Notes

Reaction equation

HRID 149240 reaction equation
[CH2:31]([BH-:32]([CH2:33][CH3:34])[CH2:35][CH3:36])[CH3:37].[CH2:46]1[O:47][CH2:48][CH2:49][CH2:50]1.[Li+:38].[Na+:43].[O-:39][C:40]([OH:41])=[O:42].[O:1]1[CH2:2][O:3][c:4]2[c:5]1[cH:6][cH:7][c:8]([CH2:10][N:11]1[C:12](=[O:30])[CH:13]3[C:14]([CH3:28])([CH3:29])[N:15]([CH3:27])[CH:16]([c:20]4[cH:21][cH:22][c:23]([Br:26])[cH:24][cH:25]4)[CH:17]3[C:18]1=[O:19])[cH:9]2.[OH:44][OH:45]>>[O:1]1[CH2:2][O:3][c:4]2[c:5]1[cH:6][cH:7][c:8]([CH2:10][N:11]1[CH:12]([OH:30])[CH:13]3[C:14]([CH3:28])([CH3:29])[N:15]([CH3:27])[CH:16]([c:20]4[cH:21][cH:22][c:23]([Br:26])[cH:24][cH:25]4)[CH:17]3[C:18]1=[O:19])[cH:9]2

Participants

8

Reactant 7

HCID 769Bicarbonate IonHCID 784Hydrogen PeroxideHCID 923Sodium ionHCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 2723994TriethylboranuideHCID 187050565-(1,3-benzodioxol-5-ylmethyl)-1-(4-bromophenyl)-2,3,3-trimethyl-3a,6a-dihydro-1H-pyrrolo[3,4-c]pyrrole-4,6-dione

Product 1

HCID 536625595-(1,3-Benzodioxol-5-ylmethyl)-1-(4-bromophenyl)-4-hydroxy-2,3,3-trimethyl-1,3a,4,6a-tetrahydropyrrolo[3,4-c]pyrrol-6-one

Sources & evidence

ORD record
ord-9f947aa36878440e92a25735ec2b1cd3
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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