HCID 14986350, compound → Benzoic Acid

HRID 1494241Notes

Reaction equation

HRID 1494241 reaction equation
Cl[C:2]1[CH:3]=[C:4]([CH:8]=[CH:9][C:10]=1OCCCCCCC1C=CC=C(OCC2C=CC=CC=2)C=1OCC1C=CC=CC=1)[C:5]([OH:7])=[O:6].[H][H]>[Pd].O1CCCC1>[C:5]([OH:7])(=[O:6])[C:4]1[CH:8]=[CH:9][CH:10]=[CH:2][CH:3]=1

Participants

5

Reactant 2

HCID 14986350HCID 14986350, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 243Benzoic Acid

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8028TetrahydrofuranSolvent

Procedure

A mixture of 0.6 g of 3-chloro-4-[6-[2,3-bis(phenylmethoxy)phenyl]hexyloxy]benzoic acid and 60 mg of 10% palladium on carbon in 20 ml of tetrahydrofuran was stirred in a hydrogen atmosphere for 6 hours. Workup as in Example 36 and recrystallization from ethyl acetate-hexane gave 0.24 g, mp benzoic acid.

Workup

  1. customWorkup as in Example 36 and recrystallization from ethyl acetate-hexane

Sources & evidence

ORD record
ord-94ad0ae1535a4514b71b3d0352224edc
Source dataset
uspto-grants-1991_06
Patent number
US05025036

Reaction notes

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