Dichloromethane → Oleyl methane sulfonate

HRID 1499371Notes

Reaction equation

HRID 1499371 reaction equation
[CH2:1]([OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].C(Cl)Cl.[CH3:23][S:24](Cl)(=[O:26])=[O:25]>C(N(CC)CC)C>[CH3:23][S:24]([O:19][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])(=[O:26])=[O:25]

Participants

5

Reactant 3

HCID 6344DichloromethaneHCID 31297Methanesulfonyl chlorideHCID 5284499Oleyl Alcohol

Product 1

HCID 6016198Oleyl methane sulfonateYield 96.4%

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

Preparation A was repeated using 410 g oleyl alcohol, 2 liters DCM, 322 ml triethylamine, 194 g methane sulphonylchloride to yield 510 g (96%) oleyl methanesulphonate product.

Workup

  1. customPreparation

Sources & evidence

ORD record
ord-907c8480eb2f41e5826a86c35aba8efe
Source dataset
uspto-grants-2015_12
Patent number
US09200229B2

Reaction notes

Loading…