Aniline → HCID 178426071, compound

HRID 1531465Notes

Reaction equation

HRID 1531465 reaction equation
[H-].[Na+:2].NC1C=CC=CC=1.[CH3:10][C:11]1[CH2:15][C:14]([CH3:16])=[C:13]([CH3:17])[C:12]=1[CH3:18]>O1CCCC1>[CH3:10][C:11]1[CH:15]([Na:2])[C:14]([CH3:16])=[C:13]([CH3:17])[C:12]=1[CH3:18]

Participants

5

Reactant 3

HCID 6115AnilineHCID 24758Sodium hydride2×HCID 1381631,2,3,4-Tetramethylcyclopentadiene

Product 1

HCID 178426071HCID 178426071, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Conditions

Temperature
40 °C

Procedure

Sodium hydride (containing mineral oil; the content of sodium hydride: 60%) (3.30 g) and aniline (0.237 g) were added to the solution of tetramethylcyclopentadiene (5.01 g) dissolved in tetrahydrofuran (45 ml), and stirred at 40° C. for 4 hours. Thus, tetramethylcyclopentadienylsodium was obtained in the form of a solution in tetrahydrofuran.

Sources & evidence

ORD record
ord-f1fa9962348e442994e43d9f880188b6
Source dataset
uspto-grants-2001_03
Patent number
US06197990B1

Reaction notes

Loading…