Dimethyl Sulfoxide → Oxalic Acid

HRID 1535669Notes

Reaction equation

HRID 1535669 reaction equation
[C:1]([C:2](=[O:3])[OH:4])(=[O:5])[OH:6].[C:51](=[O:52])([OH:53])[O-:54].[CH3:56][S:57](=[O:58])[CH3:59].[Cl:7][c:8]1[cH:9][c:10]([O:16][CH:17]([CH2:18][CH2:19][CH2:20][NH:21][CH3:22])[c:23]2[cH:24][o:25][cH:26][cH:27]2)[c:11]([C:12]#[N:13])[cH:14][cH:15]1.[N-:29]=[N+:30]=[N-:31].[Na+:28].[Na+:55].[O:61]1[CH2:62][CH2:63][CH2:64][CH2:65]1.[OH2:60].[c:32]1([P:33]([c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[c:40]2[cH:41][cH:42][cH:43][cH:44][cH:45]2)[cH:46][cH:47][cH:48][cH:49][cH:50]1>>[C:1]([C:2](=[O:3])[OH:4])(=[O:5])[OH:6].[Cl:7][c:8]1[cH:9][c:10]([O:16][CH:17]([CH2:18][CH2:19][CH2:20][NH2:21])[c:23]2[cH:24][o:25][cH:26][cH:27]2)[c:11]([C:12]#[N:13])[cH:14][cH:15]1

Participants

11

Reactant 9

HCID 679Dimethyl SulfoxideHCID 769Bicarbonate IonHCID 923Sodium ion2×HCID 962WaterHCID 971Oxalic AcidHCID 8028TetrahydrofuranHCID 11776TriphenylphosphineHCID 33558AzideHCID 9814978HCID 9814978, compound

Product 2

HCID 971Oxalic AcidHCID 9814546HCID 9814546, compound

Sources & evidence

ORD record
ord-db8a7c671d06408386fe19934012842b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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