Potassium Cation → 3-(1-methyl-1H-pyrrol-2-yl)benzaldehyde

HRID 1542303Notes

Reaction equation

HRID 1542303 reaction equation
[Br:12][c:13]1[cH:14][c:15]([CH:16]=[O:17])[cH:18][cH:19][cH:20]1.[CH2:28]1[O:29][CH2:30][CH2:31][CH2:32]1.[CH3:1][n:2]1[cH:3][cH:4][cH:5][cH:6]1.[CH3:23][CH2:24][O:25][CH2:26][CH3:27].[CH3:74][CH2:75][O:76][C:77](=[O:78])[CH3:79].[CH3:7][CH2:8][CH2:9][CH2:10][Li:11].[F-:21].[K+:22].[O:80]1[CH2:81][CH2:82][O:83][CH2:84][CH2:85]1.[Pd:33]([Cl:34])[Cl:35].[c:36]1([P:37]([c:38]2[cH:39][cH:40][cH:41][cH:42][cH:43]2)[c:44]2[cH:45][cH:46][cH:47][cH:48][cH:49]2)[cH:50][cH:51][cH:52][cH:53][cH:54]1.[c:55]1([P:56]([c:57]2[cH:58][cH:59][cH:60][cH:61][cH:62]2)[c:63]2[cH:64][cH:65][cH:66][cH:67][cH:68]2)[cH:69][cH:70][cH:71][cH:72][cH:73]1>>[CH3:1][n:2]1[c:3](-[c:13]2[cH:14][c:15]([CH:16]=[O:17])[cH:18][cH:19][cH:20]2)[cH:4][cH:5][cH:6]1

Participants

12

Reactant 11

HCID 813Potassium CationHCID 3283Diethyl EtherHCID 73041-MethylpyrroleHCID 8028TetrahydrofuranHCID 8857Ethyl AcetateHCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 28179Fluoride IonHCID 312751,4-DioxaneHCID 765833-BromobenzaldehydeHCID 178418339Butyllithium

Product 1

HCID 235059913-(1-methyl-1H-pyrrol-2-yl)benzaldehyde

Sources & evidence

ORD record
ord-ab56750fbe41475086b20d14d185545b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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