HRID1554182

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8028

Tetrahydrofuran

C4H8O

HCID28486

Lithium ion

Li+

HCID568601

Ethyl 3-(trimethylsilyl)propiolate

C8H14O2Si

HCID3280088

未命名化合物

结构：N#Cc1cc(F)c(Cc2cccc(-c3ccc(F)cc3F)n2)c(F)c1

HCID57700378

未命名化合物

PRODUCTS

生成物

结构：C[Si](C)(C)C#CC(=O)C(c1cccc(-c2ccc(F)cc2F)n1)c1c(F)cc(C#N)cc1F

HCID57700365

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4376dc3f8494432abd4f6ce8991197cb
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[CH2:47]1[O:48][CH2:49][CH2:50][CH2:51]1.[CH3:26][Si:27]([N-:28][Si:29]([CH3:30])([CH3:31])[CH3:32])([CH3:33])[CH3:34].[CH3:36][Si:37]([C:38]#[C:39][C:40](=[O:41])[O:42][CH2:43][CH3:44])([CH3:45])[CH3:46].[F:1][c:2]1[c:3](-[c:9]2[cH:10][cH:11][cH:12][c:13]([CH2:15][c:16]3[c:17]([F:25])[cH:18][c:19]([C:20]#[N:21])[cH:22][c:23]3[F:24])[n:14]2)[cH:4][cH:5][c:6]([F:8])[cH:7]1.[Li+:35]>>[F:1][c:2]1[c:3](-[c:9]2[cH:10][cH:11][cH:12][c:13]([CH:15]([c:16]3[c:17]([F:25])[cH:18][c:19]([C:20]#[N:21])[cH:22][c:23]3[F:24])[C:40]([C:39]#[C:38][Si:37]([CH3:36])([CH3:45])[CH3:46])=[O:41])[n:14]2)[cH:4][cH:5][c:6]([F:8])[cH:7]1