Hydrochloric Acid → 5-Diethylamino-2-nitrosophenol hydrochloride

HRID 1594993Notes

Reaction equation

HRID 1594993 reaction equation
[CH2:1]([N:3]([CH2:11][CH3:12])[C:4]1[CH:5]=[C:6]([OH:10])[CH:7]=[CH:8][CH:9]=1)[CH3:2].[N:13](OCCC(C)C)=[O:14].C(OCC)C.[ClH:26]>C(O)CC>[ClH:26].[CH2:11]([N:3]([CH2:1][CH3:2])[C:4]1[CH:9]=[CH:8][C:7]([N:13]=[O:14])=[C:6]([OH:10])[CH:5]=1)[CH3:12]

Participants

6

Reactant 4

HCID 313Hydrochloric AcidHCID 3283Diethyl EtherHCID 70623-(Diethylamino)phenolHCID 8053Isoamyl Nitrite

Product 1

HCID 332535-Diethylamino-2-nitrosophenol hydrochloride

Reagents, catalysts & solvents 1

HCID 10311-PropanolSolvent

Procedure

0.1 mol of 3-diethylaminophenol are dissolved in 50 ml of n-propanol saturated with gaseous hydrogen chloride and, at 0° C., admixed dropwise and with stirring with 0.1 mol of isoamyl nitrite. Stirring is continued for another hour and the reaction solution is then admixed with diethyl ether, and the product which is formed is isolated by filtration with suction.

Workup

  1. waitis continued for another hour
  2. customthe product which is formed
  3. customis isolated by filtration with suction

Sources & evidence

ORD record
ord-eaae6b0564aa4c219eb57f5092b97c57
Source dataset
uspto-grants-2001_09
Patent number
US06284889B1

Reaction notes

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