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HRID1605135

反应详情

EQUATION

反应方程式

HRID 1605135 的结构方程式

REACTANTS

反应物

4
结构：c1ccccc1
HCID241

Benzene

C6H6

结构：O=C(Cl)C(=O)Cl
HCID65578

Ethanedioyl dichloride

C2Cl2O2

结构：O=C([O-])O.[Na+]
HCID516892

Sodium Bicarbonate

CHNaO3

结构：CSC(C)(C)CCCC(C)CC=CC(C)=CC(=O)O
HCID54224307

未命名化合物

PRODUCTS

生成物

1
结构：CSC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C
HCID54300429

1-Methylethyl 3,7,11-trimethyl-11-(methylthio)-2,4-dodecadienoate

C19H34O2S

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCOCC
溶剂HCID3283

Diethyl Ether

C4H10O

结构：CC(C)O
溶剂HCID3776

Isopropanol

C3H8O

PROCEDURE

实验过程

To 0.6 g. of 11-methylthio-3,7,11-trimethyldodeca-2,4-dienoic acid in 10 ml. of dry benzene is added 0.23 ml. of oxalyl chloride at room temperature with stirring. After 2 hours, isopropanol (2ml.) is added and the mixture allowed to stand at room temperature for about 2 hours. Ether and saturated sodium bicarbonate is added and the organic phase separated. The organic phase is washed with aqueous sodium bicarbonate, saturated sodium chloride, dried over calcium sulfate and evaporated to yield isopropyl 11-methylthio-3,7,11-trimethyldodeca-2,4-dienoate.

WORKUP

后处理

  1. waitto stand at room temperature for about 2 hours
  2. customthe organic phase separated
  3. washThe organic phase is washed with aqueous sodium bicarbonate, saturated sodium chloride
  4. dry with materialdried over calcium sulfate
  5. customevaporated