2-Nitropropane → HCID 178430959, compound

HRID 1607722Notes

Reaction equation

HRID 1607722 reaction equation
[N+:1]([CH:4]([CH3:6])[CH3:5])([O-:3])=O.[CH:7]1[CH:15]=[CH:14][C:13]2[C:9](=[N:10][O:11][N+]=2[O-])[CH:8]=1.C(NCC)C>O1CCCC1>[CH3:5][C:4]1([CH3:6])[N+:1]([O-:3])=[C:13]2[CH:14]=[CH:15][CH:7]=[CH:8][C:9]2=[N+:10]1[O-:11]

Participants

5

Reactant 3

HCID 3982-NitropropaneHCID 8021DiethylamineHCID 68075Benzofuroxan

Product 1

HCID 178430959HCID 178430959, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a mixture containing 2-nitropropane (10.7 g., 0.12 moles), benzofuroxan (13.6 g., 0.10 moles) and tetrahydrofuran (50 ml.) is added dropwise diethylamine (8.7 g., 0.12 mole). The reaction temperature rises during addition. Upon completion of addition, the reaction mixture is allowed to sit overnight at room temperature.

Workup

  1. additionThe reaction temperature rises during addition
  2. additionUpon completion of addition

Sources & evidence

ORD record
ord-785d365accf046d6b37486f249bd7529
Source dataset
uspto-grants-1989_09
Patent number
US04866175

Reaction notes

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