Diethanolamine → HCID 19849273, compound

HRID 1607778Notes

Reaction equation

HRID 1607778 reaction equation
F[C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][C:11]([N+:14]([O-:16])=[O:15])=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.[NH:17]([CH2:21][CH2:22][OH:23])[CH2:18][CH2:19][OH:20].C(=O)([O-])[O-].[K+].[K+]>CS(C)=O>[OH:20][CH2:19][CH2:18][N:17]([C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][C:11]([N+:14]([O-:16])=[O:15])=[CH:10][CH:9]=2)=[CH:4][CH:3]=1)[CH2:21][CH2:22][OH:23]

Participants

5

Reactant 3

HCID 8113DiethanolamineHCID 11430Potassium CarbonateHCID 964134-Fluoro-4'-nitro-1,1'-biphenyl

Product 1

HCID 19849273HCID 19849273, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Conditions

Temperature
95 °C

Procedure

A one liter three necked flask fitted with a mechanical stirrer, condenser and thermometer is charged with 21.7 g of 4-fluoro-4'-nitrobiphenyl, 31.0 g of diethanolamine, 13.8 g of potassium carbonate, 1.0 g of Aliquot 336, and 500 ml of dimethyl sulfoxide. The reaction mixture is heated at 95° C. for a period of three days, cooled, and poured into 4 litersof ice water. The crude solid product is filtered, washed with water, and dried.

Workup

  1. temperaturecooled
  2. filtrationThe crude solid product is filtered
  3. washwashed with water
  4. customdried

Sources & evidence

ORD record
ord-7e7daac6a8df4634a840c3a3164833e4
Source dataset
uspto-grants-1989_09
Patent number
US04867540

Reaction notes

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