Acetone → Anthrone

HRID 1607860Notes

Reaction equation

HRID 1607860 reaction equation
[C:1]([O:4][CH2:5][CH3:6])(=[O:3])[CH3:2].[CH3:7][C:8]([CH3:10])=[O:9].[CH2:11]([OH:13])[CH3:12].[CH3:14][OH:15].[CH:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>C(Cl)(Cl)Cl.O.CCCCCC.C(Cl)(Cl)(Cl)Cl>[CH:16]1[CH:21]=[C:12]2[C:11]([C:1]([OH:3])([OH:4])[C:2](=[O:9])[C:19]2=[CH:18][CH:17]=1)=[O:13].[CH:6]1[C:5]2[C:14](=[O:15])[C:21]3[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=3)[CH2:12][C:11]=2[CH:10]=[CH:8][CH:7]=1

Participants

11

Reactant 5

HCID 180AcetoneHCID 241BenzeneHCID 702EthanolHCID 887MethanolHCID 8857Ethyl Acetate

Product 2

HCID 7018AnthroneHCID 10236Ninhydrin

Reagents, catalysts & solvents 4

HCID 962WaterSolventHCID 5943Carbon TetrachlorideSolventHCID 6212ChloroformSolventHCID 8058HexaneSolvent

Procedure

The individual BBM-1675 components show solubility and color reactions similar to each other. For example, they are soluble in chloroform, ethyl acetate, acetone, ethanol and methanol, slightly soluble in benzene and water, and insoluble in n-hexane and carbon tetrachloride. They give positive reactions with ferric chloride, Ehrlich and Tollen's reagents butnegative responses in Sakaguchi, ninhydrin and anthrone tests.

Sources & evidence

ORD record
ord-fba8d9fbe24044acb434406df1efec34
Source dataset
uspto-grants-1989_09
Patent number
US04868117

Reaction notes

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