Hexachloroethane → HCID 14949194, compound

HRID 1613846Notes

Reaction equation

[Cl:1]C(Cl)(Cl)C(Cl)(Cl)Cl.C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(N(CC)CC)C.[CH3:35][Si:36]([CH3:49])([CH3:48])[NH:37][S:38]([C:41]1[CH:46]=[CH:45][C:44]([F:47])=[CH:43][CH:42]=1)(=O)=[O:39]>>[CH3:35][Si:36]([CH3:49])([CH3:48])[N:37]=[S:38]([Cl:1])([C:41]1[CH:46]=[CH:45][C:44]([F:47])=[CH:43][CH:42]=1)=[O:39]

Participants

Reactant 4

HCID 6214Hexachloroethane

HCID 8471Triethylamine

HCID 11776Triphenylphosphine

HCID 149491894-Fluoro-N-(trimethylsilyl)benzene-1-sulfonamide2×

Product 1

HCID 14949194HCID 14949194, compound

Procedure

The reactants used in the general procedure were hexachloroethane (0.0953 mol, 23.02 g), triphenylphosphine (0.0963 mol, 25.51 g), triethylamine (0.0991 mol, 12.5 ml), and a mixture of N-mono- and N,N-bis(trimethylsilyl sulfonamides (3c) and (5c) containing about 89.5% monosilylsulfonamide (3c) (0.0881 mol, 21.76 g).

Sources & evidence

ORD record: ord-173244f6f8ad4ca19d588b462e3b7972
Source dataset: uspto-grants-1993_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05194557

Reaction notes

Loading…