Hexachloroethane → HCID 14949190, compound

HRID 1613848Notes

Reaction equation

HRID 1613848 reaction equation
[Cl:1]C(Cl)(Cl)C(Cl)(Cl)Cl.C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(N(CC)CC)C.[CH3:35][Si:36]([CH3:44])([CH3:43])[NH:37][S:38]([CH2:41][CH3:42])(=O)=[O:39]>C(Cl)(Cl)Cl>[CH3:35][Si:36]([CH3:44])([CH3:43])[N:37]=[S:38]([Cl:1])([CH2:41][CH3:42])=[O:39]

Participants

6

Reactant 4

HCID 6214HexachloroethaneHCID 8471TriethylamineHCID 11776TriphenylphosphineHCID 14949186N-(Trimethylsilyl)ethanesulfonamide

Product 1

HCID 14949190HCID 14949190, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Hexachloroethane (0.1110 mol, 26.81 g), triphenylphosphine (0.1121 mol, 29.70 g), triethylamine (0.1110 mol, 15.7 mL), monosilylsulfonamide (3f) (0.1110 mol, 20.1 g). 1H NMR signals (90 MHz, CHCl3): 0.00 (s, 9H), 1.27 (t, 3H), 3.23 (q, 2H).

Sources & evidence

ORD record
ord-c5232614a8594e2da876361adb01bf01
Source dataset
uspto-grants-1993_03
Patent number
US05194557

Reaction notes

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