Dimethylformamide → Tert-butyl-(3-chlorobiphenyl-4-ylethynyl)dimethylsilane

HRID 162505Notes

Reaction equation

[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[C:8]#[CH:9].[CH3:31][CH2:32][N:33]([CH2:34][CH3:35])[CH2:36][CH3:37].[Cu:43][I:44].[F:10][C:11]([F:12])([F:13])[S:14]([O:15][c:16]1[c:17]([Cl:28])[cH:18][c:19](-[c:22]2[cH:23][cH:24][cH:25][cH:26][cH:27]2)[cH:20][cH:21]1)(=[O:29])=[O:30].[O:38]=[CH:39][N:40]([CH3:41])[CH3:42]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[C:8]#[C:9][c:16]1[c:17]([Cl:28])[cH:18][c:19](-[c:22]2[cH:23][cH:24][cH:25][cH:26][cH:27]2)[cH:20][cH:21]1

Participants

Reactant 5

HCID 6228Dimethylformamide

HCID 8471Triethylamine

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 2757281(tert-Butyldimethylsilyl)acetylene

HCID 180010793-Chlorobiphenyl-4-yl trifluoromethanesulfonate

Product 1

HCID 68816298Tert-butyl-(3-chlorobiphenyl-4-ylethynyl)dimethylsilane

Sources & evidence

ORD record: ord-df1c760d871544068972bb28a4253e7e
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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