Cyclohexanecarboxylic acid → HCID 22564104, compound

HRID 1638838Notes

Reaction equation

HRID 1638838 reaction equation
[CH:1]1([C:7]([OH:9])=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH:10]1(CO)[CH2:15]CCC[CH2:11]1>[Sn]=O.C(O)(C)C>[CH:10]([C:1]1([C:7]([OH:9])=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)([CH3:15])[CH3:11]

Participants

5

Reactant 2

HCID 7413Cyclohexanecarboxylic acidHCID 7507Cyclohexanemethanol

Product 1

HCID 22564104HCID 22564104, compound

Reagents, catalysts & solvents 2

HCID 88989TIN OXIDE (SnO)CatalystHCID 3776IsopropanolSolvent

Procedure

The reaction between cyclohexane carboxylic acid and isopropanol was conducted under the same conditions as in Example 1, except that 1 g of hydrous tin oxide catalyst prepared in Example C was used in place of 2 g of the hydrous zirconium oxide catalyst used in Example 1. It was discovered by gas chromatography that cyclohexyl methanol was formed at a conversion rate of 95% and selectivity of 39%. Isopropyl cyclohexane carboxylic acid was also obtained as a by-product in an amount of 41%.

Workup

  1. customwas formed at a conversion rate of 95% and selectivity of 39%

Sources & evidence

ORD record
ord-269bf9d0e15d4ae9872659bfd28933c8
Source dataset
uspto-grants-1989_11
Patent number
US04880937

Reaction notes

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