Methane → HCID 19801168, compound

HRID 1646615Notes

Reaction equation

HRID 1646615 reaction equation
[CH2:1]([C:4]1[CH:12]=[CH:11][CH:10]=[C:9]2[C:5]=1[CH2:6][CH2:7][C:8]2=[O:13])[CH:2]=[CH2:3].C>C(O)C.[Rh]>[CH2:1]([C:4]1[CH:12]=[CH:11][CH:10]=[C:9]2[C:5]=1[CH2:6][CH2:7][C:8]2=[O:13])[CH2:2][CH3:3]

Participants

5

Reactant 2

HCID 297MethaneHCID 19801174HCID 19801174, compound

Product 1

HCID 19801168HCID 19801168, compoundYield 94.6%

Reagents, catalysts & solvents 2

HCID 23948RhodiumCatalystHCID 702EthanolSolvent

Procedure

1.63 g of 4-(2-propenyl)-1-indanone is dissolved in 300 ml of anhydrous ethanol and 400 mg of rhodium at 5% on active charcoal and hydrogenated at ambient temperature and ambient pressure for 3/4 hour. After filtering on celite, the filtrate is washed with ethanol and evaporated to dryness, and 1.56 g of expected product is obtained.

Workup

  1. filtrationAfter filtering on celite
  2. washthe filtrate is washed with ethanol
  3. customevaporated to dryness

Sources & evidence

ORD record
ord-c0c78295377a4533940621875516aa4f
Source dataset
uspto-grants-1993_01
Patent number
US05180741

Reaction notes

Loading…