Water → HCID 53929801, compound

HRID 1649028Notes

Reaction equation

HRID 1649028 reaction equation
[C:1]([C:4]1[CH:9]=[C:8]([C:10](=[O:12])[CH3:11])[C:7]([OH:13])=[CH:6][C:5]=1[NH2:14])(=[O:3])[CH3:2].C([O-])([O-])=O.[K+].[K+].[CH2:21](Br)[CH:22]=[CH2:23].O>CN(C)C=O>[CH2:23]([O:13][C:7]1[CH:6]=[C:5]([C:4]([C:1](=[O:3])[CH3:2])=[CH:9][C:8]=1[C:10](=[O:12])[CH3:11])[NH2:14])[CH:22]=[CH2:21]

Participants

6

Reactant 4

HCID 962WaterHCID 7841Allyl bromideHCID 11430Potassium CarbonateHCID 20230855Ethanone, 1,1′-(4-amino-6-hydroxy-1,3-phenylene)bis-

Product 1

HCID 53929801HCID 53929801, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Treatment of the product of step (b) (1.5 g) with K2CO3 (1 equivalent) and allyl bromide (2 equivalents) in dimethylformamide (20 ml) at 70° C. for 21/2 hours followed by dilution with water at 70° C. afforded the sub-title product, as a pale yellow solid (83%) mp 131°-134°.

Workup

  1. customat 70° C.
  2. custom2 hours

Sources & evidence

ORD record
ord-2987dc3d1c0e4b079a0d6c514c3ea034
Source dataset
uspto-grants-1983_11
Patent number
US04414416

Reaction notes

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