Water → HCID 14848514, compound

HRID 1651776Notes

Reaction equation

HRID 1651776 reaction equation
[C:1]([C:5]([Br:8])(Br)[Br:6])([F:4])([F:3])[F:2].[Cl:9][C:10]1[CH:17]=[CH:16][CH:15]=[CH:14][C:11]=1[CH:12]=[O:13].O>CN(C=O)C.[Zn]>[Br:6][C:5]([Br:8])([C:1]([F:4])([F:3])[F:2])[CH:12]([C:11]1[CH:14]=[CH:15][CH:16]=[CH:17][C:10]=1[Cl:9])[OH:13]

Participants

6

Reactant 3

HCID 962WaterHCID 69962-ChlorobenzaldehydeHCID 677181,1,1-Tribromo-2,2,2-trifluoroethane

Product 1

HCID 14848514HCID 14848514, compound

Reagents, catalysts & solvents 2

HCID 23994ZincCatalystHCID 6228DimethylformamideSolvent

Procedure

83.5 g of CF3CBr3 in anhydrous DMF and 28 g of 2-chlorobenzaldehyde were reacted under a nitrogen atmosphere. The mixture was brought to 5° C. and zinc in powder (g. 16.0) was added to it slowly. Then the mixture was let reach the room temperature and kept under stirring for 6 hours. The mixture was poured into water and extracted three times with ethyl ether.

Workup

  1. customwas brought to 5° C.
  2. customthe room temperature
  3. extractionextracted three times with ethyl ether

Sources & evidence

ORD record
ord-d6478588fc50402ea4ecf86ec6e72f3e
Source dataset
uspto-grants-1990_05
Patent number
US04929772

Reaction notes

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