Potassium Carbonate → HCID 20077546, compound

HRID 1655070Notes

Reaction equation

HRID 1655070 reaction equation
C(=O)([O-])[O-].[K+].[K+].C1OCCOCCOCCOCCOCCOC1.[CH2:25]([SH:28])[CH:26]=[CH2:27].F[C:30]1[C:31]([S:36]([NH2:39])(=[O:38])=[O:37])=[N:32][CH:33]=[CH:34][CH:35]=1>C(#N)C>[CH2:25]([S:28][C:30]1[C:31]([S:36]([NH2:39])(=[O:38])=[O:37])=[N:32][CH:33]=[CH:34][CH:35]=1)[CH:26]=[CH2:27]

Participants

6

Reactant 4

HCID 11430Potassium CarbonateHCID 13367Allyl MercaptanHCID 2855718-Crown-6HCID 199579303-Fluoropyridine-2-sulfonamide

Product 1

HCID 20077546HCID 20077546, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

33.2 g (0.24 mol) of potassium carbonate as well as 1.32 g (0.005 mol) of 18-crown-6 and 15.8 g (0.17 mol) of 80% allylmercaptan in 50 ml of acetonitrile are added to a solution, cooled to +5° C., of 17.62 g (0.1 mol) of 3-fluoropyridin-2-ylsulfonamide in 400 ml of acetonitrile.

Sources & evidence

ORD record
ord-97281074cd22435e96a3c9e35c1b664a
Source dataset
uspto-grants-1995_04
Patent number
US05410063

Reaction notes

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