Tetrahydrofuran → HCID 86757765, compound

HRID 1699106Notes

Reaction equation

[Cl:1][C:2]([Cl:12])([O:4][C:5](=[O:11])[O:6][C:7]([Cl:10])([Cl:9])[Cl:8])[Cl:3].[O:13]1[CH2:17][CH2:16][CH2:15][CH2:14]1>>[Cl:1][C:2]([Cl:3])([O:4][C:5](=[O:11])[O:6][C:7]([Cl:10])([Cl:8])[Cl:9])[Cl:12].[O:13]1[CH2:17][CH2:16][CH2:15][CH2:14]1

Participants

Reactant 2

HCID 8028Tetrahydrofuran

HCID 94429Triphosgene

Product 1

HCID 86757765HCID 86757765, compound

Procedure

44.5 g (150 mmol) of triphosgene (98% pure according to HPLC) were dissolved in 120 ml of absolute tetrahydrofuran (THF) in a 250 ml dropping funnel having a pressure balance. In so doing, no heating or gas evolution was observed. About 150 ml of triphosgene/THF solution were obtained.

Sources & evidence

ORD record: ord-f58428745c3542198865da14a6aa8938
Source dataset: uspto-grants-2002_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06344565B1

Reaction notes

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