huagongshe.com
HRID1702208

反应详情

EQUATION

反应方程式

HRID 1702208 的结构方程式

REACTANTS

反应物

2
结构：CCCCI
HCID10962

1-Iodobutane

C4H9I

结构：CC(C)(C)OC(=O)[C@@H]1CNC(=O)N1C(=O)OCc1ccccc1
HCID11067160

未命名化合物

PRODUCTS

生成物

1
结构：CCCCN1C[C@@H](C(=O)OC(C)(C)C)N(C(=O)OCc2ccccc2)C1=O
HCID56608950

未命名化合物

收率 89.1%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[O]=[Ag]
催化剂HCID92152

未命名化合物

结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

6.4 g of tert.-butyl (4S)-3-benzyloxycarbonyl-2-oxo-imidazolidine-4-carboxylate, 8.6 g of silver oxide, 18.4 g of n-butyl iodide and 100 ml of dimethylformamide are treated in the same manner as described in Example 1-(2). 6.7 g of tert.-butyl (4S)-1-n-butyl-3-benzyloxycarbonyl-2-oxo-imidazolidine-4-carboxylate are obtained as colorless syrup.