Sodium hydride → HCID 54248458, compound

HRID 1704272Notes

Reaction equation

HRID 1704272 reaction equation
[Cl:1][C:2]([F:10])=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]Cl.[CH2:11]1[O:19][C:18]2[CH:17]=[CH:16][C:15]([OH:20])=[CH:14][C:13]=2[O:12]1.[H-].[Na+]>CN(C)C=O>[Cl:1][C:2]([F:10])=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][O:20][C:15]1[CH:16]=[CH:17][C:18]2[O:19][CH2:11][O:12][C:13]=2[CH:14]=1

Participants

5

Reactant 3

HCID 24758Sodium hydrideHCID 68289SesamolHCID 54070391HCID 54070391, compound

Product 1

HCID 54248458HCID 54248458, compoundYield 63%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Operating as described in Example 8 (part B), from 3 g of 1,7-dichloro-1-fluoro-1-heptene, 2.14 g of 3,4-methylendioxyphenol, 0.69 g of NaH and 30 ml of N,N-dimethylformamide there were obtained 2.8 g of the product of the above-cited formula, a colorless oil.

Sources & evidence

ORD record
ord-861272eaded643ee97ba6dc99b8f9de2
Source dataset
uspto-grants-1978_11
Patent number
US04126623

Reaction notes

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